소개글
학사논문입니다.
Debrominatino of vic-dibromides, vic-dihalides.
목차
introduction
Experiment
Mechanism
result
discussion
본문내용
Short reaction time, mild reaction condition.
No side product yields.
High yields obtained.
Good chemoselectivity which not reacts with Ester or Carbonyl groups, so yields corresponding products.
*
Reductive debromination of vic-dibromides to alkenes with bis(cyclopetadienyl)titanium(IV) dichloride-indium system (Bull, Korean Chem. Soc. (2001), 22, 537)
Reductive dehalogenation of aliphatic vic-dihalides with metal samarium in a methanolic medium (Reiko Yamada and Nobuyuki Negoro, Tetrahedron Lett. (1999) 37,9318)
Ultrasound in synthetic organic chemistry ,Timothy J. Mason, [Chemical Society Reviews, 1997,26,443]
Nickel mediated double bond formation from vic-dibromides and ethyl magnesium bromide C, Corrado Malanga, Laura A.
참고 자료
Reductive debromination of vic-dibromides to alkenes with bis(cyclopetadienyl)titanium(IV) dichloride-indium system (Bull, Korean Chem. Soc. (2001), 22, 537)
Reductive dehalogenation of aliphatic vic-dihalides with metal samarium in a methanolic medium (Reiko Yamada and Nobuyuki Negoro, Tetrahedron Lett. (1999) 37,9318)
Ultrasound in synthetic organic chemistry ,Timothy J. Mason, [Chemical Society Reviews, 1997,26,443]
Stereo selective debromination of aryl-substituted vic-dibromides with indium metal , Brindaba C. Ranu, Sakar K. Guchhait and Arunkanti Sarkar , [Chem. Commun., [1998], 2113]
A new efficient commercial iron mediated debromination of aryl substituted vic-dibromide ; Ashim J. Thakur, Anima Boruah, Bipul Baruah and Jagir S. Sandhu, [Synthetic Communications, [2000],30,157,
Nickel mediated double bond formation from vic-dibromides and ethyl magnesium bromide C, Corrado Malanga, Laura A. Aronica, Luciano L:ardicci, ; Tetrahedron Letters, [1995] , 36, 50, 9189]
An efficient bromination of alkenes using cerium(IV) ammonium nitrate (CAN) and potassium bromide ; Vijay Nair, Sreeletha B. Panicker, Anu Augustine, Tesmol G. George, Siji Thomas, M. Vairamani ; [ Tetrahedron 57 (2001) 7417]
A facile and efficient method for the debromination of vic-dibromides to alkenes with bicl3/indium system ; Byung Woo Yoo,jong Ho Kim, and Min Hye Yang ; [Bull. Korean Chem. Soc. 2010]