Equilibrium and Dynamic Adsorption of Methylene Blue from Aqueous Solutions by Surface Modified Activated Carbons

서지정보

ㆍ발행기관 : 한국탄소학회 ㆍ수록지정보 : Carbon letters / 5권 / 4호
ㆍ저자명 : Meenakshi Goyal, Sukhmehar Singh, Roop C. Bansal

영어 초록

The equilibrium and dynamic adsorption of methylene blue from aqueous solutions by activated carbons have been studied. The equilibrium studies have been carried out on two samples of activated carbon fibres and two samples of granulated activated carbons. These activated carbons have different BET surface areas and are associated with varying amounts of carbon oxygen surface groups. The amounts of these surface groups was enhanced by oxidation with HNO3 and O2 gas at 350℃ and decreased by degassing at increasing temperatures of 400˚, 650˚ and 950℃. The adsorption increases on oxidation of the carbon surface and decreases on degassing. The increase in adsorption has been attributed to the formation of acidic carbon-oxygen surface groups and the decrease in adsorption on degassing to their elimination. The dynamic adsorption studies have been carried out on the two granulated activated carbons using two 50 mm diameter glass columns at a feed concentration of 300 mg/L and at different hydraulic loading rates (HLR) and bed heights. The minimum achievable concentrations are comparatively lower while the adsorption capacities are higher for GAC-S under the same operating conditions. The adsorption capacity of a carbon increases with increase in HLR but the rate of increase decreases at higher HLR values.

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