강화상 나노입자의 용액 반응성이 구리 도금 박막에 미치는 영향
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서지정보
ㆍ발행기관 : 한국재료학회
ㆍ수록지정보 : 한국재료학회지 / 23권 / 12호
ㆍ저자명 : 박지은, 오민주, 김이슬, 이동윤
ㆍ저자명 : 박지은, 오민주, 김이슬, 이동윤
영어 초록
To understand how reactivity between reinforcing nanoparticles and aqueous solution affects electrodeposited Cu thin films, two types of commercialized cerium oxide (ceria, CeO2) nanoparticles were used with copper sulfate electrolyte to form in-situ nanocomposite films. During this process, we observed variation in colors and pH of the electrolyte depending on the manufacturer. Ceria aqueous solution and nickel sulfate (NiSO4) aqueous solutions were also used for comparison. We checked several parameters which could be key factors contributing to the changes, such as the oxidation number of Cu, chemical impurities of ceria nanoparticles, and so on. Oxidation number was checked by salt formation by chemical reaction between CuSO4 solution and sodium hydroxide (NaOH) solution. We observed that the color changed when H2SO4 was added to the CuSO4 solution. The same effect was obtained when H2SO4 was mixed with ceria solution; the color of ceria solution changed from white to yellow. However, the color of NiSO4 solution did not show any significant changes. We did observe slight changes in the pH of the solutions in this study. We did not obtain firm evidence to explain the changes observed in this study, but changes in the color of the electrolyte might be caused by interaction of Cu ion and the by-product of ceria. The mechanical properties of the films were examined by nanoindentation, and reaction between ceria and electrolyte presumably affect the mechanical properties of electrodeposited copper films. We also examined their crystal structures and optical properties by X-ray diffraction (XRD) and UV-Vis spectroscopy.참고 자료
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