A Kinetic Analysis of the Thermal Degradation of Pyrolytic Heavy Oils obtained from Kiln Pyrolysis Process
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- 2016.06.07
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서지정보
ㆍ발행기관 : 한국열환경공학회
ㆍ수록지정보 : 열환경공학 / 8권 / 2호
ㆍ저자명 : Kyong Hwan Lee, Woo-Teck Kwo, Sea Cheon Oh
목차
1. Introduction
2. Kinetic Analysis
3. Results and Discussion
4. Conclusion
References
한국어 초록
The kinetic analysis of the thermal degradation of pyrolytic heavy oils obtained from mixed wasteplastics by kiln pyrolysis process has been studied by conventional thermogravimetric technique withvarious heating rates in nitrogen atmosphere. Results of kinetic analysis show that the activationenergies are 24.4~26.5 kJ/mol and the reaction orders are 1.0~1.25, respectively. To verify theeffectiveness of the kinetic analysis method used in this work, the experimental values werecompared with those of the numerical integration results using kinetic parameters obtained in thiswork. It was found that the kinetic analysis method used in this work gave the reliable kineticparameters of the thermal degradation of pyrolytic heavy oils.
영어 초록
The kinetic analysis of the thermal degradation of pyrolytic heavy oils obtained from mixed waste
plastics by kiln pyrolysis process has been studied by conventional thermogravimetric technique with
various heating rates in nitrogen atmosphere. Results of kinetic analysis show that the activation
energies are 24.4~26.5 kJ/mol and the reaction orders are 1.0~1.25, respectively. To verify the
effectiveness of the kinetic analysis method used in this work, the experimental values were
compared with those of the numerical integration results using kinetic parameters obtained in this
work. It was found that the kinetic analysis method used in this work gave the reliable kinetic
parameters of the thermal degradation of pyrolytic heavy oils.
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