Hierarchically porous carbon derived from tobacco waste by one‑step molten salt carbonization for supercapacitor

서지정보

ㆍ발행기관 : 한국탄소학회 ㆍ수록지정보 : Carbon letters / 32권 / 1호
ㆍ저자명 : Yuxuan Liu, Xinhua Cheng, Shenghui Zhang

목차

Abstract
1 Introduction
2 Experimental
2.1 Materials and chemicals
2.2 Carbonization process
2.3 Preparation of electrodes and electrochemical measurements
2.4 Characterization
3 Results and discussion
3.1 Morphology and structure characterization of carbon materials
3.2 Electrochemical characterization of carbon materials
4 Conclusions
Acknowledgements
References

영어 초록

High-performance carbon materials were prepared via a one-step molten salt carbonization of tobacco waste used as electrode materials for supercapacitors. Carbon material prepared by carbonization for 3 h in molten CaCl2 at 850 °C exhibits hierarchically porous structure and ideal capacitive behavior. In a three-electrode configuration with 1 mol L− 1 H2SO4 aqueous solution, it delivers specific capacitance of 196.5 F g− 1 at 0.2 A g− 1, energy density of 27.2 Wh kg− 1 at 0.2 A g− 1, power density of 983.5 W kg− 1 at 2 A g− 1, and excellent cyclic stability with 94% capacitance retention after 5000 charge–discharge cycles at 1 A g− 1. Moreover, in a symmetrical two-electrode configuration with 6 mol L− 1 KOH aqueous solution, it delivers specific capacitance of 111.1 F g− 1 at 0.2 A g− 1, energy density of 3.8 Wh kg− 1 at 0.2 A g− 1, and power density of 482.0 W kg− 1 at 2 A g− 1. The relationship between hierarchically porous structure and capacitive performance is also discussed.

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