chelate and macrocyclic effect
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- 2015.05.11
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- 2013.04
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목차
1. Chelate
2. Common Ligands
3. Nomenclature
4. Chelate effect
5. Kinetic Chelate effect
6. Macrocyclic ligand
7. Macrocyclic effect
Reference
본문내용
Chelate ligand :
two or more points of attachment to metal atoms are called Chelate ligand
* ligand ; Ion or molecule that binds to a central metal atom to form a coordination complex.
<중 략>
Nomenclature
1. The positive ion comes first, followed by the negative ion.
Ex) diamminesilver(Ⅰ) chloride, [Ag(NH3)2]Cl
potassium hexacyanoferrate(Ⅲ), K3[Fe(CN)6]
2. The inner coordination sphere is enclosed in square brackets in the formula. Within the coordination sphere, the ligands are named before the metal, but in formulas the metal ion is written first.
참고 자료
Gary L, Miessler, Donald A. Tarr, 2004, Inorganic Chemistry third edition, Pearson Education, pp304-309, pp326-328, pp457-458
Fredrick P Hinz, Dale W Margerum ,inorganic Chemistry, 1974 , Vol. 13, No. 12, pp2941-2949
Mutsudo Kodama, Eiichi Kimura, 1975, J.C.S Dalton, pp1720-1724
Dermot W Bruce, 1992, Inorganic Materials, John Wiley&Sons, pp9-10